Crystal structure of mer-tris{2,6-difluoro-3-[5-(2-fluorophenyl)pyridin-2-yl-κN]pyridin-4-yl-κC4}iridium(III) dichloromethane hemisolvate n-hexane hemisolvate

Crystal structure of mer-tris{2,6-difluoro-3-[5-(2-fluorophenyl)pyridin-2-yl-κN]pyridin-4-yl-κC4}iridium(III) dichloromethane hemisolvate n-hexane hemisolvate

The asymmetric unit of the title compound, [Ir(C17H11F2N2)3]·0.5CH3(CH2)4CH3·0.5CH2Cl2, comprises one IrIII atom, three 2,6-difluoro-3-[5-(2-fluorophenyl)pyridin-2-yl]pyridin-4-yl ligands and half each of an n-hexane and a dichloromethane solvent molecule located about crystallographic inversion cen...

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Bibliographic Details
Main Authors: Youngjin Kang, Ki-Min Park, Jinho Kim
Format: Article
Language:English
Published: International Union of Crystallography 2017-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
iridium(III) complex
C,N-chelating ligand
mer-C3N3 coordination set
hydrogen bonds
C—F...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017016759

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http://scripts.iucr.org/cgi-bin/paper?S2056989017016759

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