Synthesis of Stable and Soluble One-Handed Helical Homopoly(substituted acetylene)s without the Coexistence of Any Other Chiral Moieties via Two-Step Polymer Reactions in Membrane State: Molecular Design of the Starting Monomer

Synthesis of Stable and Soluble One-Handed Helical Homopoly(substituted acetylene)s without the Coexistence of Any Other Chiral Moieties via Two-Step Polymer Reactions in Membrane State: Molecular Design of the Starting Monomer

A soluble and stable one-handed helical poly(substituted phenylacetylene) without the coexistence of any other chiral moieties was successfully synthesized by asymmetric-induced polymerization of a chiral monomer followed by two-step polymer reactions in membrane state: (1) removing the chiral group...

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Bibliographic Details
Main Authors: Takashi Kaneko, Masahiro Teraguchi, Yu Zang, Lijia Liu, Yuriko Kakihana, Takeshi Namikoshi, Hongge Jia, Shingo Hadano, Toshiki Aoki, Yunosuke Abe
Format: Article
Language:English
Published: MDPI AG 2012-01-01
Series:Molecules
Subjects:
one-handed helicity
chirality
polymer reaction
membrane
phenylacetylene
asymmetric polymerization
solubility
Online Access:http://www.mdpi.com/1420-3049/17/1/433/

Internet

http://www.mdpi.com/1420-3049/17/1/433/

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