An unexpected oxidation: NaK5Cl2(S2O6)2 revisited

The title compound, NaK5Cl2(S2O6)2 [systematic name: sodium pentapotassium dichloride bis(dithionate)], arose as an unexpected product from an organic synthesis that used dithionite (S2O42−) ions as a reducing agent to destroy excess permanganate ions. Compared to the previous study [Stanley (1953)....

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Bibliographic Details
Main Authors: William T. A. Harrison, M. John Plater
Format: Article
Language:English
Published: International Union of Crystallography 2017-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017000494