Selective preparation of tetrasubstituted fluoroalkenes by fluorine-directed oxetane ring-opening reactions

The selective ring-opening reaction of fluoroalkylidene-oxetanes was directed by the presence of the fluorine atom, enabling a two-step access to tetrasubstituted fluoroalkenes with excellent geometry control. Despite its small van der Waals radii electronic, rather than steric influences of the flu...

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Bibliographic Details
Main Authors: Clément Q. Fontenelle, Thibault Thierry, Romain Laporte, Emmanuel Pfund, Thierry Lequeux
Format: Article
Language:English
Published: Beilstein-Institut 2020-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.16.160