Homoconjugation vs. Exciton Coupling in Chiral α,β-Unsaturated Bicyclo[3.3.1]nonane Dinitrile and Carboxylic Acids

Homoconjugation vs. Exciton Coupling in Chiral α,β-Unsaturated Bicyclo[3.3.1]nonane Dinitrile and Carboxylic Acids

The chiroptical properties of enantiomerically pure bicyclo[3.3.1]nona-2,6-diene-2,6-dicarbonitrile and related acids were studied by circular dichroism spectroscopy and theoretical computations. A consideration of the molecular structure of the synthesized difunctional compounds revealed that chrom...

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Bibliographic Details
Main Authors: Gintautas Bagdžiūnas, Eugenijus Butkus, Sigitas Stončius
Format: Article
Language:English
Published: MDPI AG 2014-07-01
Series:Molecules
Subjects:
circular dichroism
conformational analysis
TD-DFT calculations
transannular interactions
homoconjugation
Online Access:http://www.mdpi.com/1420-3049/19/7/9893

Internet

http://www.mdpi.com/1420-3049/19/7/9893

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