Six tris(bipyridyl)iron(II) complexes with 2-substituted 1,1,3,3-tetracyanopropenide, perchlorate and tetrafluoridoborate anions; order versus disorder, hydrogen bonding and C—N...π interactions

Six tris(bipyridyl)iron(II) complexes with 2-substituted 1,1,3,3-tetracyanopropenide, perchlorate and tetrafluoridoborate anions; order versus disorder, hydrogen bonding and C—N...π interactions

Structures are reported for six closely related salts of tris(bipyridyl)iron(II) cations, namely tris(2,2′-bipyridine)iron(II) bis(1,1,3,3-tetracyano-2-methoxypropenide) 0.776-hydrate, [Fe(C10H8N2)3](C8H3N4O)2.0.776H2O, (I), tris(2,2′-bipyridine)iron(II) 1,1,3,3-tetracyano-2-(propylsulfanyl)propenid...

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Bibliographic Details
Main Authors: Abderezak Addala, Zouaoui Setifi, Yukio Morimoto, Beñat Artetxe, Takashi Matsumoto, Juan M. Gutiérrez-Zorrilla, Christopher Glidewell
Format: Article
Language:English
Published: International Union of Crystallography 2018-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
synthesis
tris(bipyridyl)iron(II) complexes
polynitrile anions
crystal structure
disorder
hydrogen bonding
C—N...π interactions
supramolecular assembly
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018015426

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http://scripts.iucr.org/cgi-bin/paper?S2056989018015426

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