Oxidation of ruthenium and iridium metal by XeF2 and crystal structure determination of [Xe2F3][RuF6]∙XeF2 and [Xe2F3][MF6] (M = Ru, Ir)
Salts containing [Xe2F3]+ cations and [MF6]- anions (M = Ru, Ir) were synthesized by the oxidation of metal with excess of XeF2 in anhydrous hydrogen fluoride (aHF) as a solvent. Single crystals of [Xe2F3][RuF6]∙XeF2, [Xe2F3][RuF6] and [Xe2F3][IrF6] were grown by slow evaporation of the solvent. [Xe...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Slovenian Chemical Society
2016-05-01
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Series: | Acta Chimica Slovenica |
Subjects: | |
Online Access: | https://journals.matheo.si/index.php/ACSi/article/view/2373 |