Oxidation of ruthenium and iridium metal by XeF2 and crystal structure determination of [Xe2F3][RuF6]∙XeF2 and [Xe2F3][MF6] (M = Ru, Ir)

Salts containing [Xe2F3]+ cations and [MF6]- anions (M = Ru, Ir) were synthesized by the oxidation of metal with excess of XeF2 in anhydrous hydrogen fluoride (aHF) as a solvent. Single crystals of [Xe2F3][RuF6]∙XeF2, [Xe2F3][RuF6] and [Xe2F3][IrF6] were grown by slow evaporation of the solvent. [Xe...

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Bibliographic Details
Main Authors: Melita Tramšek, Evgeny Goreshnik, Gašper Tavčar
Format: Article
Language:English
Published: Slovenian Chemical Society 2016-05-01
Series:Acta Chimica Slovenica
Subjects:
Online Access:https://journals.matheo.si/index.php/ACSi/article/view/2373