Superelectrophilic carbocations: preparation and reactions of a substrate with six ionizable groups

A substrate has been prepared having two triarylmethanol centers and four pyridine-type substituent groups. Upon ionization in the Brønsted superacid CF3SO3H, the substrate undergoes two types of reactions. In the presence of only the superacid, the highly ionized intermediate(s) provide a double cy...

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Bibliographic Details
Main Authors: Sean H. Kennedy, Makafui Gasonoo, Douglas A. Klumpp
Format: Article
Language:English
Published: Beilstein-Institut 2019-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.15.153