Quantification of High Resolution Pulsed RF GDOES Depth Profiles for Mo/B<sub>4</sub>C/Si Nano-Multilayers

Pulsed-radio frequency glow discharge optical emission spectrometry (Pulsed-RF-GDOES) has exhibited great potential for high resolution (HR) depth profiling. In this paper, the measured GDOES depth profile of 60 × Mo (3 nm)/B<sub>4</sub>C (0.3 nm)/Si (3.7 nm) was quantified by employing...

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Main Authors: Hao Yang, Songyou Lian, Patrick Chapon, Yibing Song, Jiangyong Wang, Congkang Xu
Format: Article
Language:English
Published: MDPI AG 2021-05-01
Series:Coatings
Subjects:
Online Access:https://www.mdpi.com/2079-6412/11/6/612
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spelling doaj-1b19b31e14a34d0b862a69bcd9fb36172021-06-01T00:41:11ZengMDPI AGCoatings2079-64122021-05-011161261210.3390/coatings11060612Quantification of High Resolution Pulsed RF GDOES Depth Profiles for Mo/B<sub>4</sub>C/Si Nano-MultilayersHao Yang0Songyou Lian1Patrick Chapon2Yibing Song3Jiangyong Wang4Congkang Xu5Department of Chemistry, Shantou University, 243 Daxue Road, Shantou 515063, ChinaDepartment of Physics, Shantou University, 243 Daxue Road, Shantou 515063, ChinaHORIBA France, Bd Thomas Gobert, 91120 Palaiseau, FranceDepartment of Chemistry, Shantou University, 243 Daxue Road, Shantou 515063, ChinaDepartment of Physics, Shantou University, 243 Daxue Road, Shantou 515063, ChinaDepartment of Physics, Shantou University, 243 Daxue Road, Shantou 515063, ChinaPulsed-radio frequency glow discharge optical emission spectrometry (Pulsed-RF-GDOES) has exhibited great potential for high resolution (HR) depth profiling. In this paper, the measured GDOES depth profile of 60 × Mo (3 nm)/B<sub>4</sub>C (0.3 nm)/Si (3.7 nm) was quantified by employing the newly extended Mixing-Roughness-Information depth (MRI) model. We evaluated the influences of the thickness and sputtering rate on the depth profile of very thin layers. We demonstrated that a method using the full width at half maximum (FWHM) value of the measured time-concentration profile for determining the sputtering rate and the corresponding thickness was not reliable if preferential sputtering took place upon depth profiling.https://www.mdpi.com/2079-6412/11/6/612GDOES depth profilingpreferential sputteringMRI modelnano-multilayers
collection DOAJ
language English
format Article
sources DOAJ
author Hao Yang
Songyou Lian
Patrick Chapon
Yibing Song
Jiangyong Wang
Congkang Xu
spellingShingle Hao Yang
Songyou Lian
Patrick Chapon
Yibing Song
Jiangyong Wang
Congkang Xu
Quantification of High Resolution Pulsed RF GDOES Depth Profiles for Mo/B<sub>4</sub>C/Si Nano-Multilayers
Coatings
GDOES depth profiling
preferential sputtering
MRI model
nano-multilayers
author_facet Hao Yang
Songyou Lian
Patrick Chapon
Yibing Song
Jiangyong Wang
Congkang Xu
author_sort Hao Yang
title Quantification of High Resolution Pulsed RF GDOES Depth Profiles for Mo/B<sub>4</sub>C/Si Nano-Multilayers
title_short Quantification of High Resolution Pulsed RF GDOES Depth Profiles for Mo/B<sub>4</sub>C/Si Nano-Multilayers
title_full Quantification of High Resolution Pulsed RF GDOES Depth Profiles for Mo/B<sub>4</sub>C/Si Nano-Multilayers
title_fullStr Quantification of High Resolution Pulsed RF GDOES Depth Profiles for Mo/B<sub>4</sub>C/Si Nano-Multilayers
title_full_unstemmed Quantification of High Resolution Pulsed RF GDOES Depth Profiles for Mo/B<sub>4</sub>C/Si Nano-Multilayers
title_sort quantification of high resolution pulsed rf gdoes depth profiles for mo/b<sub>4</sub>c/si nano-multilayers
publisher MDPI AG
series Coatings
issn 2079-6412
publishDate 2021-05-01
description Pulsed-radio frequency glow discharge optical emission spectrometry (Pulsed-RF-GDOES) has exhibited great potential for high resolution (HR) depth profiling. In this paper, the measured GDOES depth profile of 60 × Mo (3 nm)/B<sub>4</sub>C (0.3 nm)/Si (3.7 nm) was quantified by employing the newly extended Mixing-Roughness-Information depth (MRI) model. We evaluated the influences of the thickness and sputtering rate on the depth profile of very thin layers. We demonstrated that a method using the full width at half maximum (FWHM) value of the measured time-concentration profile for determining the sputtering rate and the corresponding thickness was not reliable if preferential sputtering took place upon depth profiling.
topic GDOES depth profiling
preferential sputtering
MRI model
nano-multilayers
url https://www.mdpi.com/2079-6412/11/6/612
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