Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (h5-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar’)amido-TiCl2/MAO (Ar’=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)

The propensity of a half-sandwich (η5-tetramethylcyclopentadienyl) dimethylsilylamido TiIV-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (Ti-8), activated by methylaluminoxane (MAO) to homopolymerize α-olefins such as ethylene, 1-hexene and styrene as well as to copolymer...

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Bibliographic Details
Main Authors: Michael R. Buchmeiser, Ingrid Reinhardt, Ulrich Decker, Sebnem Camadanli, Christa Kühnel
Format: Article
Language:English
Published: MDPI AG 2011-01-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/16/1/567/