Synthesis and crystallographic characterization of [2,2-bis(η5-pentamethylcyclopentadienyl)-3,4-bis(trimethylsilyl)-2-zirconafuran-5-one-κO5]triisobutylaluminium

Synthesis and crystallographic characterization of [2,2-bis(η5-pentamethylcyclopentadienyl)-3,4-bis(trimethylsilyl)-2-zirconafuran-5-one-κO5]triisobutylaluminium

The crystal structure of the title zwitterionic zirconocene complex containing a furanone unit, [AlZr(C10H15)2(C4H9)3(C9H18O2Si2)], is reported. On reacting a zirconafuranone with two equivalents of HAl(i-Bu)2, disproportionation of the Lewis acid results in the formation of a triisobutylaluminium f...

Full description

Bibliographic Details
Main Authors: Vladimir V. Burlakov, Vyacheslav S. Bogdanov, Perdita Arndt, Anke Spannenberg, Uwe Rosenthal, Torsten Beweries, Vladimir B. Shur
Format: Article
Language:English
Published: International Union of Crystallography 2018-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
zirconium metallocene
triisobutylaluminium
zwitterionic enolate complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018004759

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989018004759

Similar Items