Synthesis, structure, and C–H bond activation reaction of an iron(IV) terminal imido complex bearing trifluoromethyl groups

Synthesis, structure, and C–H bond activation reaction of an iron(IV) terminal imido complex bearing trifluoromethyl groups

Summary: Iron terminal imido species featuring electron-withdrawing N-substituents represent an important category of reactive metal-ligand-multiple-bond intermediates in iron-catalyzed reactions. Knowledge of them is very limited, however, as isolable complexes of this type are hard to access. Here...

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Bibliographic Details
Main Authors: Qing Liu, Linhong Long, Pengchen Ma, Yingjie Ma, Xuebing Leng, Jie Xiao, Hui Chen, Liang Deng
Format: Article
Language:English
Published: Elsevier 2021-06-01
Series:Cell Reports Physical Science
Subjects:
iron
nitrogen ligand
carbene ligand
metal-ligand multiple bond
hydrogen atom abstraction
imido
Online Access:http://www.sciencedirect.com/science/article/pii/S2666386421001545

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http://www.sciencedirect.com/science/article/pii/S2666386421001545

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