Formaldehyde-1,1″-(phenylphosphinidenesulfide)bis[(2<i>S</i>)-2-[(1<i>R</i>)-1-(methylamino)-ethyl]]ferrocene-aminal

Formaldehyde-1,1″-(phenylphosphinidenesulfide)bis[(2<i>S</i>)-2-[(1<i>R</i>)-1-(methylamino)-ethyl]]ferrocene-aminal

In the course of an ongoing synthetic project, we observed an unprecedented reactivity of <i>N</i>-methyl groups in bis(<i>N</i>,<i>N</i>-dimethylaminoethylferrocenyl)phenylphosphinesulfide upon treatment with manganese dioxide (MnO<sub>2</sub>). The i...

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Bibliographic Details
Main Authors: Philipp Honegger, Michael Widhalm
Format: Article
Language:English
Published: MDPI AG 2019-11-01
Series:Molbank
Subjects:
ferrocene
manganese dioxide
oxidation
planar chirality
diaza macrocycle
c–n bond formation
Online Access:https://www.mdpi.com/1422-8599/2019/4/M1090

Internet

https://www.mdpi.com/1422-8599/2019/4/M1090

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