Novel Countercation in MMX-Type Mixed-Valence Chain Compound: Coexistence of Neutral and Protonated Amino Substituents

Novel Countercation in MMX-Type Mixed-Valence Chain Compound: Coexistence of Neutral and Protonated Amino Substituents

The first MMX-type quasi-one-dimensional (Q1D) Pt chain complex (MMX chain) that contains a mono-protonated diamine as countercation, {o-(H3NC6H4NH2)}4[Pt2(pop)4I]·H2O (pop = P2H2O52–), was synthesized. According to the crystal structural analysis, –NH2 group was hydrogen-bonded to either lattice H2...

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Bibliographic Details
Main Authors: Hiroaki Iguchi, Deli Jiang, Jimin Xie, Shinya Takaishi, Masahiro Yamashita
Format: Article
Language:English
Published: MDPI AG 2011-10-01
Series:Polymers
Subjects:
MMX-chain complex
1D structure
partial deprotonation
hydrogen bond
Online Access:http://www.mdpi.com/2073-4360/3/4/1652/
Description
Summary:The first MMX-type quasi-one-dimensional (Q1D) Pt chain complex (MMX chain) that contains a mono-protonated diamine as countercation, {o-(H3NC6H4NH2)}4[Pt2(pop)4I]·H2O (pop = P2H2O52–), was synthesized. According to the crystal structural analysis, –NH2 group was hydrogen-bonded to either lattice H2O molecule or –NH3+ group in addition to typical hydrogen bond between –NH3+ group and pop ligand. To control the partial deprotonation of the countercation will be an important method for achieving the high-conductive MMX-chain polymer by the hole doping.
ISSN:2073-4360

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