Novel Countercation in MMX-Type Mixed-Valence Chain Compound: Coexistence of Neutral and Protonated Amino Substituents
The first MMX-type quasi-one-dimensional (Q1D) Pt chain complex (MMX chain) that contains a mono-protonated diamine as countercation, {o-(H3NC6H4NH2)}4[Pt2(pop)4I]·H2O (pop = P2H2O52–), was synthesized. According to the crystal structural analysis, –NH2 group was hydrogen-bonded to either lattice H2...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2011-10-01
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| Series: | Polymers |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2073-4360/3/4/1652/ |