[1,3]/[1,4]-Sulfur atom migration in β-hydroxyalkylphosphine sulfides

β-Hydroxyalkylphosphine sulfides undergo [1,3]- or [1,4]-sulfur atom phosphorus-to-carbon migration in the presence of Lewis or Brønsted acids. The direction of sulfur atom migration depends on the type of acid used for the reaction. In the presence of a Brønsted acid, mainly [1,3]-rearrangement is...

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Bibliographic Details
Main Authors: Katarzyna Włodarczyk, Piotr Borowski, Marek Stankevič
Format: Article
Language:English
Published: Beilstein-Institut 2020-01-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
dft
Online Access:https://doi.org/10.3762/bjoc.16.11