Crystal structure of cis-bis[4-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ2N1,S]nickel(II) monohydrate tetrahydrofuran disolvate

Crystal structure of cis-bis[4-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamidato-κ2N1,S]nickel(II) monohydrate tetrahydrofuran disolvate

The reaction of NiII acetate tetrahydrate with the ligand 4-phenyl-2-(1,2,3,4-tetrahydronaphthalen-1-ylidene)hydrazinecarbothioamide in a 2:1 molar ratio yielded the title compound, [Ni(C16H16N3S)2]·2C4H8O·H2O. The deprotonated ligands act as N,S-donors, forming five-membered metallacycles with the...

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Bibliographic Details
Main Authors: Adriano Bof de Oliveira, Bárbara Regina Santos Feitosa, Christian Näther, Inke Jess
Format: Article
Language:English
Published: International Union of Crystallography 2014-08-01
Series:Acta Crystallographica Section E
Subjects:
thiosemicarbazone complex
anagostic interactions
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814016079

Internet

http://scripts.iucr.org/cgi-bin/paper?S1600536814016079

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