Di-μ-chlorido-bis({4-[bis(trimethylsilyl)amino]-6-chloro-2,2,8,8-tetramethyl-5,7-bis(trimethylsilyl)-3,5,7-triaza-4,6-diphospha-2,8-disilanon-3-en-4-ido-κ2P,P′}palladium(II)) diethyl ether disolvate

Di-μ-chlorido-bis({4-[bis(trimethylsilyl)amino]-6-chloro-2,2,8,8-tetramethyl-5,7-bis(trimethylsilyl)-3,5,7-triaza-4,6-diphospha-2,8-disilanon-3-en-4-ido-κ2P,P′}palladium(II)) diethyl ether disolvate

The title compound, [Pd2(C18H54Cl2N4P2Si6)2Cl2]·2C4H10O, features a dinuclear chloride-bridged palladium complex bearing two equivalents of the novel monoanionic mixed valent (λ3-P)—N—(λ5-P) ligand. A metal catalyzed coupling of two aminoiminophosphines and a shift of one chlorine from the metal to...

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Bibliographic Details
Main Authors: Martha Höhne, Bernd H. Müller, Anke Spannenberg, Uwe Rosenthal
Format: Article
Language:English
Published: International Union of Crystallography 2016-06-01
Series:IUCrData
Subjects:
crystal structure
dinuclear palladium complex
chloride-bridged complex
metal catalyzed coupling
phosphorous ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461600986X

Internet

http://scripts.iucr.org/cgi-bin/paper?S241431461600986X

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