Probing ultrafast C–Br bond fission in the UV photochemistry of bromoform with core-to-valence transient absorption spectroscopy

Probing ultrafast C–Br bond fission in the UV photochemistry of bromoform with core-to-valence transient absorption spectroscopy

UV pump–extreme UV (XUV) probe femtosecond transient absorption spectroscopy is used to study the 268 nm induced photodissociation dynamics of bromoform (CHBr3). Core-to-valence transitions at the Br(3d) absorption edge (∼70 eV) provide an atomic scale perspective of the reaction, sensitive to chang...

Full description

Bibliographic Details
Main Authors: Benjamin W. Toulson, Mario Borgwardt, Han Wang, Florian Lackner, Adam S. Chatterley, C. D. Pemmaraju, Daniel M. Neumark, Stephen R. Leone, David Prendergast, Oliver Gessner
Format: Article
Language:English
Published: AIP Publishing LLC and ACA 2019-09-01
Series:Structural Dynamics
Online Access:http://dx.doi.org/10.1063/1.5113798

Internet

http://dx.doi.org/10.1063/1.5113798

Similar Items