[Bis(Trimethylsilyl)Methyl]Lithium and -Sodium: Solubility in Alkanes and Complexes with O- and N- Donor Ligands

[Bis(Trimethylsilyl)Methyl]Lithium and -Sodium: Solubility in Alkanes and Complexes with O- and N- Donor Ligands

In contrast to alkyl compounds of lithium, which play an important role in organometallic chemistry, the corresponding heavier alkali metal compounds are less investigated. These compounds are mostly insoluble in inert solvents or undergo solvolysis in coordinating solvents due to their high reactiv...

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Bibliographic Details
Main Authors: Markus von Pilgrim, Mihail Mondeshki, Jan Klett
Format: Article
Language:English
Published: MDPI AG 2017-06-01
Series:Inorganics
Subjects:
lithium
sodium
alkali metals
organometallic
alkyl
NMR spectroscopy
X-ray diffraction
cryoscopy
aggregation
Online Access:http://www.mdpi.com/2304-6740/5/2/39

Internet

http://www.mdpi.com/2304-6740/5/2/39

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