One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties

One-Pot Synthesis of Cu(II) Complex with Partially Oxidized TTF Moieties

The one-pot synthesis of a Cu(II) complex with partially oxidized tetrathiafulvalene (TTF) moieties in its capping MT-Hsae-TTF ligands, [CuII(MT-sae-TTF)2] [CuICl2] was realized by the simultaneous occurrence of Cu(II) complexation and CuIICl2 mediated oxidation of TTF moieties. The crystal structur...

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Bibliographic Details
Main Authors: Hiroki Oshio, Takuya Shiga, Kiyotaka Mitsumoto, Ryosuke Kitabatake, Hiroyuki Nishikawa
Format: Article
Language:English
Published: MDPI AG 2012-07-01
Series:Crystals
Subjects:
TTF-based metal complex
Schiff base-type TTF-ligand
partial oxidation of TTF
one-pot synthesis
electrical conductivity
π-d interaction
Online Access:http://www.mdpi.com/2073-4352/2/3/935

Internet

http://www.mdpi.com/2073-4352/2/3/935

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