Controlled fluoridation of amorphous carbon films deposited at reactive plasma conditions

A study of the correlations between plasma parameters, gas ratios, and deposited amorphous carbon film properties is presented. The injection of a C4F8/Ar/N2 mixture of gases was successfully used in an inductively coupled plasma system for the preparation of amorphous carbon films with different fl...

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Bibliographic Details
Main Authors: Yoffe Alexander, Zon Ilya, Feldman Yishay, Shelukhin Victor
Format: Article
Language:English
Published: Sciendo 2015-09-01
Series:Materials Science-Poland
Subjects:
Online Access:http://www.degruyter.com/view/j/msp.2015.33.issue-3/msp-2015-0088/msp-2015-0088.xml?format=INT
Description
Summary:A study of the correlations between plasma parameters, gas ratios, and deposited amorphous carbon film properties is presented. The injection of a C4F8/Ar/N2 mixture of gases was successfully used in an inductively coupled plasma system for the preparation of amorphous carbon films with different fluoride doping at room-temperature, using silicon as a substrate. This coating was formed at low-pressure and low-energy using an inductively coupled plasma process. A strong dependence between the ratios of gases during deposition and the composition of the substrate compounds was shown. The values of ratios between Ar (or Ar+N2) and C4F8 - 1:1 and between N2 and Ar - 1:2 in the N2/Ar/C4F8 mixture were found as the best for low fluoridated coatings. In addition, an example of improving the etch-passivation in the Bosch procedure was described. Scanning electron microscopy with energy dispersive spectroscopy options, X-ray diffraction, and X-ray reflectivity were used for quantitative analysis of the deposited films.
ISSN:2083-134X