Giant thermal expansion of a two-dimensional supramolecular network triggered by alkyl chain motion

The intrinsic flexibility of molecules opens the door to unusual physical properties. Now, a large thermal expansion coefficient of 980 ± 110 × 10−6 K−1 is observed by scanning probe microscopy in a supramolecular network on a gold surface.

Bibliographic Details
Main Authors: Sebastian Scherb, Antoine Hinaut, Rémy Pawlak, J. G. Vilhena, Yi Liu, Sara Freund, Zhao Liu, Xinliang Feng, Klaus Müllen, Thilo Glatzel, Akimitsu Narita, Ernst Meyer
Format: Article
Language:English
Published: Nature Publishing Group 2020-02-01
Series:Communications Materials
Online Access:https://doi.org/10.1038/s43246-020-0009-2