The Chiral 1:2 Adduct (<i>S</i>)<sub>S</sub>(<i>S</i>)<sub>C</sub>(−)<sub>589</sub>-Ethyl 2-Phenylbutyl Sulphide-Mercury (II) Chloride:(−)<sub>589</sub>[(<i>S</i>)<sub>S</sub>(<i>S</i>)<sub>C</sub>-Et(2-PhBu)S.(HgCl<sub>2</sub>)<sub>2</sub>]. Stereoselective Synthesis, Asymmetric Oxidation, Crystal and Molecular Structure and Circular Dichroism Spectra

The Chiral 1:2 Adduct (<i>S</i>)<sub>S</sub>(<i>S</i>)<sub>C</sub>(−)<sub>589</sub>-Ethyl 2-Phenylbutyl Sulphide-Mercury (II) Chloride:(−)<sub>589</sub>[(<i>S</i>)<sub>S</sub>(<i>S</i>)<sub>C</sub>-Et(2-PhBu)S.(HgCl<sub>2</sub>)<sub>2</sub>]. Stereoselective Synthesis, Asymmetric Oxidation, Crystal and Molecular Structure and Circular Dichroism Spectra

Optically active (−)<sub>589</sub>ethyl (<i>S</i>)-2-phenylbutyl thioether, (−)(<i>S</i>)<sub>C</sub>-Et(PhBu)S (<b>I</b>), and its new diastereoisomeric mercury (II) chloride adduct, 1:2, (−)[(<i>S</i>)<sub>S</sub>(...

Full description

Bibliographic Details
Main Authors: Paolo Biscarini, Ivano Bilotti, Francesco Ferranti, Alessia Bacchi, Giancarlo Pelizzi, Marian Mikołajczyk, Jozef Drabowicz
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Molecules
Subjects:
sulphide mercury chloride complex
chirality
X-ray crystallography
asymmetric oxidation
circular dichroism
absolute configuration
Online Access:https://www.mdpi.com/1420-3049/25/15/3398

Internet

https://www.mdpi.com/1420-3049/25/15/3398

Similar Items