Modulation of Conformational Preferences of Heteroaromatic Ethers and Amides through Protonation and Ionization: Charge Effect

Modulation of Conformational Preferences of Heteroaromatic Ethers and Amides through Protonation and Ionization: Charge Effect

Abstract Multiple approaches reveal the strong effects of a positive charge introduced by protonation or ionization on the conformation of o‐heteroaromatic ethers and amides. The ethers and amides containing an ortho‐N heteroatom are syn‐preferring while those containing an ortho‐O or ortho‐S hetero...

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Bibliographic Details
Main Authors: Dr. Wenshuai Dai, Dr. Zhe Zhang, Prof. Yikui Du
Format: Article
Language:English
Published: Wiley-VCH 2019-07-01
Series:ChemistryOpen
Subjects:
conformational modulation
heteroaromatic ethers
heteroaromatic amides
protonation
ionization
Online Access:https://doi.org/10.1002/open.201900103

Internet

https://doi.org/10.1002/open.201900103

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