Ruthenium(η6,η1-arene-CH2-NHC) Catalysts for Direct Arylation of 2-Phenylpyridine with (Hetero)Aryl Chlorides in Water

Ruthenium(η6,η1-arene-CH2-NHC) Catalysts for Direct Arylation of 2-Phenylpyridine with (Hetero)Aryl Chlorides in Water

A series of new benzimidazolium halides were synthesized in good yields as unsymmetrical N-heterocyclic carbene (NHC) precursors containing the N–CH2–arene group. The benzimidazolium halides were readily converted into ruthenium(II)–NHC complexes with the general formula [RuCl2(η6,η1–arene–CH2–NHC)]...

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Bibliographic Details
Main Authors: Nazan Kaloğlu, İsmail Özdemir, Nevin Gürbüz, Hakan Arslan, Pierre H. Dixneuf
Format: Article
Language:English
Published: MDPI AG 2018-03-01
Series:Molecules
Subjects:
homogeneous catalysis
ruthenium
N-heterocyclic carbene
2-phenylpyridine
direct arylation
single crystal structure
Online Access:http://www.mdpi.com/1420-3049/23/3/647

Internet

http://www.mdpi.com/1420-3049/23/3/647

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