Transition metal-free oxidative and deoxygenative C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes

Transition metal-free oxidative and deoxygenative C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyl lithium as an efficient synthetic approach to azaheterocyclic carboranes

The direct C–H functionalization methodology has first been applied to perform transition metal-free C–H/C–Li cross-couplings of 2H-imidazole 1-oxides with carboranyllithium. This atom- and step-economical approach, based on one-pot reactions of nucleophilic substitution of hydrogen (SNH) in non-aro...

Full description

Bibliographic Details
Main Authors: Lidia A. Smyshliaeva, Mikhail V. Varaksin, Pavel A. Slepukhin, Oleg N. Chupakhin, Valery N. Charushin
Format: Article
Language:English
Published: Beilstein-Institut 2018-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
carboranes
C–H functionalization
C–H/C–Li cross-coupling
2H-imidazole 1-oxide
nucleophilic substitution of hydrogen (SNH)
Online Access:https://doi.org/10.3762/bjoc.14.240

Internet

https://doi.org/10.3762/bjoc.14.240

Similar Items