Improved Metathesis Lifetime: Chelating Pyridinyl-Alcoholato Ligands in the Second Generation Grubbs Precatalyst

Improved Metathesis Lifetime: Chelating Pyridinyl-Alcoholato Ligands in the Second Generation Grubbs Precatalyst

Hemilabile ligands can release a free coordination site “on demand” of an incoming nucleophilic substrate while occupying it otherwise. This is believed to increase the thermal stability and activity of catalytic systems and therefore prevent decomposition via free coordination sites. In this invest...

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Bibliographic Details
Main Authors: Jean I. du Toit, Margaritha Jordaan, Carlijn A. A. Huijsmans, Johannes H. L. Jordaan, Cornelia G. C. E. van Sittert, Hermanus C. M. Vosloo
Format: Article
Language:English
Published: MDPI AG 2014-04-01
Series:Molecules
Subjects:
second generation grubbs precatalyst
pyridinyl-alcoholato ligand
1-octene metathesis
lifetime
Online Access:http://www.mdpi.com/1420-3049/19/5/5522

Internet

http://www.mdpi.com/1420-3049/19/5/5522

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