Insights in the Rhodium-Catalyzed Tandem Isomerization-Hydroformylation of 10-Undecenitrile: Evidence for a Fast Isomerization Regime
The tandem isomerization-hydroformylation of 10-undecenitrile (1) into the corresponding linear aldehyde (2) with a Rh-biphephos system was studied and the formation of internal olefin isomers (1-int-x) was monitored over time. The existence of an “isomerization phenomenon” was evidenced, where fast...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2018-04-01
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| Series: | Catalysts |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2073-4344/8/4/148 |