Chemical instability at chalcogenide surfaces impacts chalcopyrite devices well beyond the surface

Anion vacancies are a hurdle for technologies based on chalcogenide semiconductors and topological insulators. Even at room temperature, oxidation and cyanide etching can lead to selenium vacancies in CuInSe2 photovoltaic material but suitable post deposition treatments can mitigate their effect.

Bibliographic Details
Main Authors: Diego Colombara, Hossam Elanzeery, Nicoleta Nicoara, Deepanjan Sharma, Marcel Claro, Torsten Schwarz, Anna Koprek, Max Hilaire Wolter, Michele Melchiorre, Mohit Sood, Nathalie Valle, Oleksandr Bondarchuk, Finn Babbe, Conrad Spindler, Oana Cojocaru-Miredin, Dierk Raabe, Phillip J. Dale, Sascha Sadewasser, Susanne Siebentritt
Format: Article
Language:English
Published: Nature Publishing Group 2020-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-17434-8