Expanding the scope of metal-free enantioselective allylic substitutions: Anthrones
The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities.
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
2015-11-23.
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| Subjects: | |
| Online Access: | Get fulltext Get fulltext |
| LEADER | 01131 am a22002293u 4500 | ||
|---|---|---|---|
| 001 | 385722 | ||
| 042 | |a dc | ||
| 100 | 1 | 0 | |a Ceban, Victor |e author |
| 700 | 1 | 0 | |a Tauchman, Jiri |e author |
| 700 | 1 | 0 | |a Meazza, Marta |e author |
| 700 | 1 | 0 | |a Gallagher, Greg |e author |
| 700 | 1 | 0 | |a Light, Mark E. |e author |
| 700 | 1 | 0 | |a Gergelitsová, Ivana |e author |
| 700 | 1 | 0 | |a Veselý, Jan |e author |
| 700 | 1 | 0 | |a Rios, Ramon |e author |
| 245 | 0 | 0 | |a Expanding the scope of metal-free enantioselective allylic substitutions: Anthrones |
| 260 | |c 2015-11-23. | ||
| 856 | |z Get fulltext |u https://eprints.soton.ac.uk/385722/1/srep16886.pdf | ||
| 856 | |z Get fulltext |u https://eprints.soton.ac.uk/385722/2/Supporting%252520information%252520Highly%252520enantioselective%252520anthrone%252520addition%252520to%252520MBH%252520corrected.pdf | ||
| 520 | |a The highly enantioselective asymmetric allylic alkylation of Morita-Baylis-Hillman carbonates with anthrones is presented. The reaction is simply catalyzed by cinchona alkaloid derivatives affording the final alkylated products in good yields and excellent enantioselectivities. | ||
| 540 | |a cc_by_4 | ||
| 655 | 7 | |a Article | |