Aza-macrocyclic complexes of Group 1 cations:synthesis, structures and density functional theory study
The Group 1 complexes, [M(Me6[18]aneN6)][BArF] (M = Li-Cs; Me6[18]aneN6 = 1,4,7,10,13,16-hexamethyl-1,4,7,10,13,16-hexaazacyclooctadecane; BArF = tetrakis{3,5-bis(trifluoromethyl)-phenyl}borate), are obtained in high yield by reaction of the macrocycle with M[BArF] in anhydrous CH2Cl2 solution, and...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
2015-08-21.
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| Subjects: | |
| Online Access: | Get fulltext |