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01153 am a22001573u 4500 |
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380329 |
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|a Green, Robert Aaron
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|a Brown, Richard C. D.
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|a Pletcher, Derek
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|a Leach, Stuart
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|a N-heterocyclic carbene-mediated oxidative electrosynthesis of esters in a microflow cell
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|c 2015-06-15.
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|z Get fulltext
|u https://eprints.soton.ac.uk/380329/1/N-Heterocyclic%2520Carbene-Mediated%2520Oxidative%2520Electrosynthesis%2520of%2520Esters%2520in%2520a%2520Microflow%2520Cell.pdf
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|a An efficient N-heterocyclic carbene (NHC)-mediated oxidative esterification of aldehydes has been achieved in an undivided microfluidic electrolysis cell at ambient temperature. Productivities of up to 4.3 g h?1 in a single pass are demonstrated, with excellent yields and conversions for 19 examples presented. Notably, the oxidative acylation reactions were shown to proceed with a 1:1 stoichiometry of aldehyde and alcohol (for primary alcohols), with remarkably short residence times in the electrolysis cell (<13 s), and without added electrolyte.
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