Tantalum(V) fluoride complexes of thio- and seleno-ether ligands and a comparison with the TaX5 (X=Cl or Br) analogues
Reaction of TaF5 with SMe2 and RS(CH2)2SR (R = Me, Et or iPr) in anhydrous CH2Cl2 solution produce colourless, extremely moisture sensitive crystals of [TaF4(SMe2)4][TaF6] and [TaF4{RS(CH2)2SR}2][TaF6] respectively, which contain eight-coordinate cations and octahedral anions, whereas TaF5 reacts wi...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
2012-05.
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| Subjects: | |
| Online Access: | Get fulltext |