Biopolymer electrolyte based on derivatives of cellulose from kenaf bast fiber

Abstract: A cellulose derivative, carboxymethyl cellulose (CMC), was synthesized by the reaction of cellulose from kenaf bast fiber with monochloroacetic acid. A series of biopolymer electrolytes comprised of the synthesized CMC and ammonium acetate (CH3COONH4) were prepared by the solution-casting...

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Bibliographic Details
Main Authors: Ahmad, A. (Author), Mohamed, N.S (Author), Rani, M.S.A (Author), Rudhziah, S. (Author)
Format: Article
Language:English
Published: MDPI AG 2014
Subjects:
Online Access:View Fulltext in Publisher
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LEADER 02039nam a2200277Ia 4500
001 10.3390-polym6092371
008 220112s2014 CNT 000 0 und d
020 |a 20734360 (ISSN) 
245 1 0 |a Biopolymer electrolyte based on derivatives of cellulose from kenaf bast fiber 
260 0 |b MDPI AG  |c 2014 
856 |z View Fulltext in Publisher  |u https://doi.org/10.3390/polym6092371 
856 |z View in Scopus  |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-84910037962&doi=10.3390%2fpolym6092371&partnerID=40&md5=d50c1f064dcad4af101dac36eab58848 
520 3 |a Abstract: A cellulose derivative, carboxymethyl cellulose (CMC), was synthesized by the reaction of cellulose from kenaf bast fiber with monochloroacetic acid. A series of biopolymer electrolytes comprised of the synthesized CMC and ammonium acetate (CH3COONH4) were prepared by the solution-casting technique. The biopolymer-based electrolyte films were characterized by Fourier Transform Infrared spectroscopy to investigate the formation of the CMC-CH3COONH4 complexes. Electrochemical impedance spectroscopy was conducted to obtain their ionic conductivities. The highest conductivity at ambient temperature of 5.77 × 10-4 S cm-1 was obtained for the electrolyte film containing 20 wt% of CH3COONH4. The biopolymer electrolyte film also exhibited electrochemical stability up to 2.5 V. These results indicated that the biopolymer electrolyte has great potential for applications to electrochemical devices, such as proton batteries and solar cells. © 2014 by the authors. 
650 0 4 |a Ammonium acetate 
650 0 4 |a Biopolymer electrolyte 
650 0 4 |a Biopolymer electrolytes 
650 0 4 |a Electrochemical stabilities 
650 0 4 |a electrochemical stability 
650 0 4 |a Fourier transform infrared spectroscopy 
650 0 4 |a Fourier transform infrared spectroscopy (FTIR) 
650 0 4 |a Kenaf bast fibers 
700 1 0 |a Ahmad, A.  |e author 
700 1 0 |a Mohamed, N.S.  |e author 
700 1 0 |a Rani, M.S.A.  |e author 
700 1 0 |a Rudhziah, S.  |e author 
773 |t Polymers