Electrophotocatalytic Si-H Activation Governed by Polarity-Matching Effects
Trialkylsilanes are important building blocks in organic synthesis; however, their widespread use in redox chemistry is limited by their high oxidation potentials and comparably high bond dissociation energies (BDEs) of Si-H and α-Si-C-H bonds (>92 kcal mol-1). Herein, we report a new strategy fo...
Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
Chinese Chemical Society
2022
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Subjects: | |
Online Access: | View Fulltext in Publisher |