Effect of deposition potential on the structure, electrocatalytic activity and stability of Pt films for methanol oxidation
The effect of deposition potential on the structure and electrocatalytic properties of Pt films electrodeposited on Ti was investigated. By controlling a constant deposition potential either at -0.15 V, -0.20 V, -0.25 V or -0.30 V, various shapes of Pt structures such as cauliflower-like, durian-lik...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Electrochemical Science Group
2017
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| Online Access: | View Fulltext in Publisher View in Scopus |
| LEADER | 01623nam a2200205Ia 4500 | ||
|---|---|---|---|
| 001 | 10.20964-2017.02.77 | ||
| 008 | 220120s2017 CNT 000 0 und d | ||
| 020 | |a 14523981 (ISSN) | ||
| 245 | 1 | 0 | |a Effect of deposition potential on the structure, electrocatalytic activity and stability of Pt films for methanol oxidation |
| 260 | 0 | |b Electrochemical Science Group |c 2017 | |
| 520 | 3 | |a The effect of deposition potential on the structure and electrocatalytic properties of Pt films electrodeposited on Ti was investigated. By controlling a constant deposition potential either at -0.15 V, -0.20 V, -0.25 V or -0.30 V, various shapes of Pt structures such as cauliflower-like, durian-like, needle-like and worm-like can be observed by FESEM. The face-centered cubic (fcc) structure of all the prepared Pt films was confirmed by XRD. The highest specific electrochemically active surface area (ECSA) was obtained for Pt films with durian-like shape prepared at -0.2 V with 6.0 m2 g-1 which gave the best catalytic activity and stability for methanol oxidation in alkaline medium. © 2017 The Authors. | |
| 650 | 0 | 4 | |a Electrocatalytic activity |
| 650 | 0 | 4 | |a Electrodeposition |
| 650 | 0 | 4 | |a Methanol oxidation |
| 650 | 0 | 4 | |a Pt films |
| 700 | 1 | 0 | |a Ab Malek, S.N. |e author |
| 700 | 1 | 0 | |a Mohd, Y. |e author |
| 773 | |t International Journal of Electrochemical Science |x 14523981 (ISSN) |g 12 2, 1561-1571 | ||
| 856 | |z View Fulltext in Publisher |u https://doi.org/10.20964/2017.02.77 | ||
| 856 | |z View in Scopus |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-85012898975&doi=10.20964%2f2017.02.77&partnerID=40&md5=c83ea51878d3476a308646d36bd670c2 | ||