Influence of thermal treatment on the properties and intermolecular interactions of epoxidized natural rubber-salt systems

The influence of thermal treatment on the thermal stability, thermal properties, dielectric properties and intermolecular interaction of binary epoxidized natural rubber (ENR)-salt systems, which may be a candidate for solid polymer electrolytes (SPEs) was investigated. Solubility of salt in ENR enh...

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Bibliographic Details
Main Authors: Abetz, V. (Author), Chan, C.H (Author), Fritz, M. (Author), Ramli, H. (Author), Zainal, N.F.A (Author)
Format: Article
Language:English
Published: De Gruyter Open Ltd 2021
Series:Pure and Applied Chemistry
Subjects:
Online Access:View Fulltext in Publisher
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LEADER 02409nam a2200493Ia 4500
001 10.1515-pac-2020-0904
008 220121s2021 CNT 000 0 und d
020 |a 00334545 (ISSN) 
245 1 0 |a Influence of thermal treatment on the properties and intermolecular interactions of epoxidized natural rubber-salt systems 
260 0 |b De Gruyter Open Ltd  |c 2021 
490 1 |a Pure and Applied Chemistry 
650 0 4 |a Centenary of macromolecules 
650 0 4 |a Crosslinked 
650 0 4 |a dielectric properties 
650 0 4 |a Dielectric properties 
650 0 4 |a epoxidized natural rubber 
650 0 4 |a Epoxidized natural rubber 
650 0 4 |a Glass transition 
650 0 4 |a glass transition temperature 
650 0 4 |a Heat treatment 
650 0 4 |a intermolecular interaction 
650 0 4 |a Intermolecular interactions 
650 0 4 |a IUPAC Polymer Division 
650 0 4 |a macrogel 
650 0 4 |a microgel 
650 0 4 |a Microgel 
650 0 4 |a Percolation networks 
650 0 4 |a Polyelectrolytes 
650 0 4 |a Rubber 
650 0 4 |a Salt content 
650 0 4 |a Salt systems 
650 0 4 |a Solid electrolytes 
650 0 4 |a Solid polymer electrolytes 
650 0 4 |a Solvents 
650 0 4 |a thermal treatment 
856 |z View Fulltext in Publisher  |u https://doi.org/10.1515/pac-2020-0904 
856 |z View in Scopus  |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-85114401316&doi=10.1515%2fpac-2020-0904&partnerID=40&md5=7da1206ac6f69ce00744a1b06f132a69 
520 3 |a The influence of thermal treatment on the thermal stability, thermal properties, dielectric properties and intermolecular interaction of binary epoxidized natural rubber (ENR)-salt systems, which may be a candidate for solid polymer electrolytes (SPEs) was investigated. Solubility of salt in ENR enhances, which may be due to the disruption of the lightly-crosslinked microgel under heat treatment. The increase in the ionic conductivities of the thermally treated ENR SPEs at constant salt content is correlated to the higher glass transition temperatures, development of percolation network and higher extent of intermolecular interactions between ENR and charged entities in this study. © 2021 IUPAC & De Gruyter. 
700 1 0 |a Abetz, V.  |e author 
700 1 0 |a Chan, C.H.  |e author 
700 1 0 |a Fritz, M.  |e author 
700 1 0 |a Ramli, H.  |e author 
700 1 0 |a Zainal, N.F.A.  |e author 
773 |t Pure and Applied Chemistry