Redox Chemistry of tris( β-diketonate)cobalt(III) Complexes: A Molecular View

Redox Chemistry of tris( β-diketonate)cobalt(III) Complexes: A Molecular View

Reduction of low spin S = 0 tris(β-diketonate)cobalt(III) complexes leads to an intermediate spin S = 3/2 anion. This electron rearrangement upon reduction could be the reason why a large peak potential difference between the reduction and re-oxidation peaks was observed during electrochemical analy...

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Bibliographic Details
Main Author: Conradie, J. (Author)
Format: Article
Language:English
Published: Institute of Physics 2022
Subjects:
% reductions
Carbon fibers
Cobalt compounds
Cyclic voltammetry
Density functional theory
Electron affinity
Group theory
Intermediate spins
Oxidation peak
Peak potentials
Polarographic analysis
Potential difference
Redox chemistry
Redox potentials
Redox reactions
Redoxpotential
Reduction
Reduction-oxidation
Re-oxidation
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