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01425nam a2200193Ia 4500 |
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10.1107-S2414314622003868 |
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220706s2022 CNT 000 0 und d |
| 020 |
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|a 24143146 (ISSN)
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| 245 |
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|a Nitrato(5,10,15,20-tetra phenyl porphinato)manganese(III)-benzene-n-hexa ne (2/1/1)
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|b International Union of Crystallography
|c 2022
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| 856 |
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|z View Fulltext in Publisher
|u https://doi.org/10.1107/S2414314622003868
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|a The crystal structure of solvated [Mn(TPP)(NO3)] (TPP = 5,10,15,20-tetra phenyl porphyrinato, C44H28N4), [Mn(C44H28N4O3)(NO3)]·0.5C6H14·0.5C6H6, has been determined in the space group Pccn. The MnIII atom has a distorted square-pyramidal environment, being coordinated by four pyrrole N atoms of the porphyrin ligand in the basal plane and an O atom of the nitrato ligand in the apical site. The MnIII atom is displaced out of the porphyrin plane by 0.22 (4) Å with the average Mn-Np distance being 2.011 (6) Å (where Np is a porphyrin N atom). The Mn-O bond length is 2.1246 (18) Å. Two kinds of inter molecular C-H⋯O hydrogen bonds exist in the crystal structure, with the apical nitrato ligands inter acting with solvent mol ecules and adjacent mol ecules, respectively. © 2022.
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|a Crystal structure
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|a Manganese(III) porphyrin
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|a Nitrate
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|a Cao, H.
|e author
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|a Li, J.
|e author
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|a Wang, J.
|e author
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| 773 |
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|t IUCrData
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