Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato} palladium(II)
In the title compound, [Pd(C15H13FNO2)2], the PdII atom is tetra-coordinated by two N atoms and two O atoms from the two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phen-oxy ligands, forming a square-planar geometry. The two N atoms and the two O atoms around the PdII atom are trans to each other...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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| Online Access: | View Fulltext in Publisher View in Scopus |
| LEADER | 01354nam a2200193Ia 4500 | ||
|---|---|---|---|
| 001 | 10.1107-S1600536811017739 | ||
| 008 | 220112s2011 CNT 000 0 und d | ||
| 020 | |a 16005368 (ISSN) | ||
| 245 | 1 | 0 | |a Bis{2-[(E)-(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phenolato} palladium(II) |
| 856 | |z View Fulltext in Publisher |u https://doi.org/10.1107/S1600536811017739 | ||
| 856 | |z View in Scopus |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-79957990669&doi=10.1107%2fS1600536811017739&partnerID=40&md5=db1ff40e3bf61301bbdadec335299654 | ||
| 520 | 3 | |a In the title compound, [Pd(C15H13FNO2)2], the PdII atom is tetra-coordinated by two N atoms and two O atoms from the two 2-[(4-fluoro-benz-yl)imino-meth-yl]-6-meth-oxy-phen-oxy ligands, forming a square-planar geometry. The two N atoms and the two O atoms around the PdII atom are trans to each other. The dihedral angle between the two fluoro-substituted benzene rings is 39.03 (6)°. The mol-ecular structure is stabilized by an intra-molecular C - H⋯O hydrogen bond. In the crystal, weak inter-molecular C - H⋯π inter-actions occur. | |
| 650 | 0 | 4 | |a Tetra |
| 700 | 1 | 0 | |a Bahron, H. |e author |
| 700 | 1 | 0 | |a Fun, H.-K. |e author |
| 700 | 1 | 0 | |a Hemamalini, M. |e author |
| 700 | 1 | 0 | |a Ibrahim, W.N.W. |e author |
| 700 | 1 | 0 | |a Mohd Tajuddin, A. |e author |
| 773 | |t Acta Crystallographica Section E: Structure Reports Online | ||