Influence of Manganese Substitution on Photocatalytic Activity of Fe3-xMnxO4 Catalyst by Heterogeneous Photo Fenton-like Reaction

In this study, the influence of manganese substitution on the photocatalytic activity of heterogeneous Fe3-xMnxO4 catalyst were investigated. The Fe3-xMnxO4 catalysts were synthesized through co-precipitation method at varies manganese (Mn) substitution ratio (x) of 0, 0.1, 0.2, 0.3, 0.4 and 0.5, re...

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Main Authors: Abdullah M.M.A.-B (Author), Adzwin Noordin, N. (Author), Aida Zubir, N. (Author), Alrozi, R. (Author), Anuar Kamaruddin, M. (Author), Edwin, E. (Author), Imam Maarof, H. (Author), Nasuha, N. (Author), Rahim S.Z.A (Author), Rosli M.F (Author), Saad M.N.M (Author), Talib M.S (Author), Zain A.M (Author)
Format: Article
Language:English
Published: Institute of Physics Publishing 2019
Subjects:
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001 10.1088-1757-899X-551-1-012114
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020 |a 17578981 (ISSN) 
245 1 0 |a Influence of Manganese Substitution on Photocatalytic Activity of Fe3-xMnxO4 Catalyst by Heterogeneous Photo Fenton-like Reaction 
260 0 |b Institute of Physics Publishing  |c 2019 
650 0 4 |a Catalyst activity 
650 0 4 |a Coprecipitation method 
650 0 4 |a Degradation 
650 0 4 |a Degradation kinetics 
650 0 4 |a First order reactions 
650 0 4 |a Green computing 
650 0 4 |a Heterogeneous photo-Fenton 
650 0 4 |a Image enhancement 
650 0 4 |a Iron oxides 
650 0 4 |a Manganese 
650 0 4 |a Manganese compounds 
650 0 4 |a Oxidation 
650 0 4 |a Photo-catalytic 
650 0 4 |a Photocatalytic activity 
650 0 4 |a Photocatalytic performance 
650 0 4 |a Photo-Fenton 
650 0 4 |a Precipitation (chemical) 
650 0 4 |a Pristine catalysts 
650 0 4 |a Reaction kinetics 
856 |z View Fulltext in Publisher  |u https://doi.org/10.1088/1757-899X/551/1/012114 
856 |z View in Scopus  |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-85071833526&doi=10.1088%2f1757-899X%2f551%2f1%2f012114&partnerID=40&md5=c78a0f1710a803a064d143beb9504c34 
520 3 |a In this study, the influence of manganese substitution on the photocatalytic activity of heterogeneous Fe3-xMnxO4 catalyst were investigated. The Fe3-xMnxO4 catalysts were synthesized through co-precipitation method at varies manganese (Mn) substitution ratio (x) of 0, 0.1, 0.2, 0.3, 0.4 and 0.5, respectively. The photocatalytic performance of the resultant catalysts were tested in photo Fenton-like degradation of AOII dye in the presence of 22Mm H2O2 at initial pH of 3. Interestingly, discoloration of 95.9% AOII was achieved at optimized x value of 0.3. Enhancement of nearly 98% was observed compared to pristine catalyst (x=0) which was able to degrade up to 48.4% only. In addition, it also demonstrated that the AOII degradation kinetic using Fe3-xMnxO4 catalyst at x=0.3 by photo Fenton-like reaction was fitted well with the first order reaction kinetic (k = 0.018 min-1 and R2 = 0.9862). Thus, it can be suggested that the substitution of Mn into the matrix of iron oxide provides a positive influence in enhancing the overall photocatalytic peformance of heterogeneous Fe3-xMnxO4 catalyst during the photo Fenton-like reaction. © 2019 Published under licence by IOP Publishing Ltd. 
700 1 0 |a Abdullah M.M.A.-B.  |e author  
700 1 0 |a Adzwin Noordin, N.  |e author  
700 1 0 |a Aida Zubir, N.  |e author  
700 1 0 |a Alrozi, R.  |e author  
700 1 0 |a Anuar Kamaruddin, M.  |e author  
700 1 0 |a Edwin, E.  |e author  
700 1 0 |a Imam Maarof, H.  |e author  
700 1 0 |a Nasuha, N.  |e author  
700 1 0 |a Rahim S.Z.A.  |e author  
700 1 0 |a Rosli M.F.  |e author  
700 1 0 |a Saad M.N.M.  |e author  
700 1 0 |a Talib M.S.  |e author  
700 1 0 |a Zain A.M.  |e author