The synthesis of some novel stilbene dimers incorporating diamide tethers: Studies in single electron transfer oxidation (FeCl3)

The synthesis of some novel stilbene dimers incorporating diamide tethers: Studies in single electron transfer oxidation (FeCl3)

The FeCl3 oxidative cascade reaction of the acetamido stilbene 1 which we reported some years ago produced the first atropodiastereomeric indolostilbene hybrid 3. By contrast, recent investigation of the oxidation of the stilbene succinamide dimer 72 (FeCl3/CH2Cl2) appears, on the basis of spectrosc...

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Bibliographic Details
Main Authors: Alehashem, M.S (Author), Ariffin, A. (Author), Qatran Al-Khdhairawi, A.A (Author), Thomas, N.F (Author)
Format: Article
Language:English
Published: Royal Society of Chemistry 2018
Subjects:
Acetamido
Cascade reactions
Chlorine compounds
Diamides
Iron compounds
Macrocyclics
Single electron transfer
Spectroscopic evidence
Succinamide
Online Access:View Fulltext in Publisher
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Description
Summary:The FeCl3 oxidative cascade reaction of the acetamido stilbene 1 which we reported some years ago produced the first atropodiastereomeric indolostilbene hybrid 3. By contrast, recent investigation of the oxidation of the stilbene succinamide dimer 72 (FeCl3/CH2Cl2) appears, on the basis of spectroscopic evidence, to have produced the bridged macrocyclic indoline 73. © The Royal Society of Chemistry 2018.
ISBN:20462069 (ISSN)
DOI:10.1039/c7ra12534h

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