Structural and functional investigation of graphene oxide-Fe 3 O 4 nanocomposites for the heterogeneous Fenton-like reaction

Graphene oxide-iron oxide (GO-Fe3O4) nanocomposites were synthesised by co-precipitating iron salts onto GO sheets in basic solution. The results showed that formation of two distinct structures was dependent upon the GO loading. The first structure corresponds to a low GO loading up to 10wt%, assoc...

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Bibliographic Details
Main Authors: Diniz Da Costa, J.C (Author), Motuzas, J. (Author), Yacou, C. (Author), Zhang, X. (Author), Zubir, N.A (Author)
Format: Article
Language:English
Published: Nature Publishing Group 2014
Online Access:View Fulltext in Publisher
View in Scopus
LEADER 01699nam a2200193Ia 4500
001 10.1038-srep04594
008 220112s2014 CNT 000 0 und d
020 |a 20452322 (ISSN) 
245 1 0 |a Structural and functional investigation of graphene oxide-Fe 3 O 4 nanocomposites for the heterogeneous Fenton-like reaction 
260 0 |b Nature Publishing Group  |c 2014 
856 |z View Fulltext in Publisher  |u https://doi.org/10.1038/srep04594 
856 |z View in Scopus  |u https://www.scopus.com/inward/record.uri?eid=2-s2.0-84898755987&doi=10.1038%2fsrep04594&partnerID=40&md5=e533c96740856fd33b5f4cb6fdcf518b 
520 3 |a Graphene oxide-iron oxide (GO-Fe3O4) nanocomposites were synthesised by co-precipitating iron salts onto GO sheets in basic solution. The results showed that formation of two distinct structures was dependent upon the GO loading. The first structure corresponds to a low GO loading up to 10wt%, associated with the beneficial intercalation of GO within Fe3O4nanoparticles and resulting in higher surface area up to 409m2g-1. High GO loading beyond 10 wt% led to the aggregation of Fe3O4 nanoparticles and the undesirable stacking of GO sheets. The presence of strong interfacial interactions (Fe-O-C bonds) between both components at low GO loading lead to 20% higher degradation of Acid Orange 7 than the Fe3O4 nanoparticles in heterogeneous Fenton-like reaction. This behaviour was attributed to synergistic structural and functional effect of the combined GO and Fe3O4 nanoparticles. 
700 1 0 |a Diniz Da Costa, J.C.  |e author 
700 1 0 |a Motuzas, J.  |e author 
700 1 0 |a Yacou, C.  |e author 
700 1 0 |a Zhang, X.  |e author 
700 1 0 |a Zubir, N.A.  |e author 
773 |t Scientific Reports