The Fourth Virial Coefficient for Hard Spheres in Even Dimension

The fourth virial coefficient is calculated exactly for a fluid of hard spheres in even dimensions. For this purpose the complete star cluster integral is expressed as the sum of two three-folded integrals only involving spherical angular coordinates. These integrals are solved analytically for any...

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Bibliographic Details
Main Author: Urrutia, I. (Author)
Format: Article
Language:English
Published: Springer 2022
Online Access:View Fulltext in Publisher
Description
Summary:The fourth virial coefficient is calculated exactly for a fluid of hard spheres in even dimensions. For this purpose the complete star cluster integral is expressed as the sum of two three-folded integrals only involving spherical angular coordinates. These integrals are solved analytically for any even dimension d, and working with existing expressions for the other terms of the fourth cluster integral, we obtain an expression for the fourth virial coefficient B4(d) for even d. It reduces to the sum of a finite number of simple terms that increases with d. © 2022, The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.
ISBN:00224715 (ISSN)
DOI:10.1007/s10955-022-02913-7