Diimine(dithiolate)platinum(ii) Chromophores: Synthesis, Spectroscopy, and Material Applications

• Main Author: Browning, Charles
• Other Authors: Omary, Mohammad A.
• Format: Others
• Language: English
• Published: University of North Texas 2014
• Subjects: Solar energy.; chromophores; spectroscopy; donor-acceptor charge transfer; Chromatophores.; Photovoltaic power systems.; Platinum.
• Online Access: https://digital.library.unt.edu/ark:/67531/metadc699877/

A series of 28 square-planar dithiol(diimine)platinum(II) chromophoric complexes have been synthesized, characterized, and evaluated for potential efficacy in sensitization of solid state photovoltaic devices to the near-infrared regions of the electromagnetic spectrum. The effect of molecular stacking in the solid state and self-association in solution are shown to influence spectral, electronic, and magnetic properties of the chromophores. Such properties are investigated in the pure form and as partners in donor-acceptor charge transfer adducts. Finally, selected chromophores have been incorporated into single layer schottky diodes as neat films and as dopants in multi-layer organic photovoltaic devices. Evaluation of the devices internal quantum efficiency and voltage-current was measured as proof of concept.