Synthesis and reactions of poly(ethynyldialkylsilanes)
A nucleophilic cleavage reaction of 2,2,5,5,8,8-hexamethyl-2,5,8-trisilanona-3,6-diyne, I, with several bases, occurs rapidly at room temperature in both polar and non-polar solvents. An attack occurs exclusively at the central silicon regardless of the steric requirements of the bases (alkyllithium...
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Format: | Others |
Language: | English |
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University of North Texas
1990
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Online Access: | https://digital.library.unt.edu/ark:/67531/metadc332501/ |