The Nature of Intermediates Produced Through Ligand-Substitution Reactions of Octahedral Metal Carbonyls
Pulsed laser time-resolved ligand-substitution photochemistry for (DTO)W(CO)4, (DTN)W(CO)4, and (NP)Mo(CO)4 (DTO = 2,2,7,7-tetramethyl-3,6-diathiaoctane; DTN = 2,2,8,8- tetramethyl-3,7-diathianonane; NP = l-diethylamino-2- diphenylphosphinoethane) proceeds via initial fission of the W-S and Mo-P bon...
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Format: | Others |
Language: | English |
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North Texas State University
1986
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Online Access: | https://digital.library.unt.edu/ark:/67531/metadc331634/ |