Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups

Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups

Mixed alkyllithium / lithium alkoxide aggregates in the form (RLi)n(ROLi)m were formed by addition of corresponding alcohol compounds at different Li/O ratios. Variable temperature 13C and 6Li NMR spectroscopy were used to verify the formation of the mixed aggregates and to study their behavior in h...

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Bibliographic Details
Main Author: Thornton, Terry L. (Terry Lee), 1962-
Other Authors: Thomas, Ruthanne Detrick
Format: Others
Language:English
Published: University of North Texas 1997
Subjects:
alkyllithim
compounds
chemistry
Organolithium compounds.
Online Access:https://digital.library.unt.edu/ark:/67531/metadc278441/
id ndltd-unt.edu-info-ark-67531-metadc278441
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spelling ndltd-unt.edu-info-ark-67531-metadc2784412020-07-15T07:09:31Z Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups Thornton, Terry L. (Terry Lee), 1962- alkyllithim compounds chemistry Organolithium compounds. Mixed alkyllithium / lithium alkoxide aggregates in the form (RLi)n(ROLi)m were formed by addition of corresponding alcohol compounds at different Li/O ratios. Variable temperature 13C and 6Li NMR spectroscopy were used to verify the formation of the mixed aggregates and to study their behavior in hydrocarbon solution. Spectra for the lithium n-propoxide / n-propyllithium and iso-butyllithium / lithium iso-butoxide systems each indicated at least one mixed aggregate. University of North Texas Thomas, Ruthanne Detrick Bott, Simon G. 1997-12 Thesis or Dissertation vi, 61 leaves : ill. Text call-no: 379 N81 no.7462 local-cont-no: 1002656305-thornton untcat: b2075473 https://digital.library.unt.edu/ark:/67531/metadc278441/ ark: ark:/67531/metadc278441 English Public Copyright Copyright is held by the author, unless otherwise noted. All rights reserved. Thornton, Terry L. (Terry Lee), 1962-
collection NDLTD
language English
format Others
sources NDLTD
topic alkyllithim
compounds
chemistry
Organolithium compounds.
spellingShingle alkyllithim
compounds
chemistry
Organolithium compounds.
Thornton, Terry L. (Terry Lee), 1962-
Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups
description Mixed alkyllithium / lithium alkoxide aggregates in the form (RLi)n(ROLi)m were formed by addition of corresponding alcohol compounds at different Li/O ratios. Variable temperature 13C and 6Li NMR spectroscopy were used to verify the formation of the mixed aggregates and to study their behavior in hydrocarbon solution. Spectra for the lithium n-propoxide / n-propyllithium and iso-butyllithium / lithium iso-butoxide systems each indicated at least one mixed aggregate.
author2 Thomas, Ruthanne Detrick
author_facet Thomas, Ruthanne Detrick
Thornton, Terry L. (Terry Lee), 1962-
author Thornton, Terry L. (Terry Lee), 1962-
author_sort Thornton, Terry L. (Terry Lee), 1962-
title Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups
title_short Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups
title_full Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups
title_fullStr Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups
title_full_unstemmed Mixed Alkyllithim/Lithium Alkoxide Aggregates with Less Sterically Crowded Alkyl Groups
title_sort mixed alkyllithim/lithium alkoxide aggregates with less sterically crowded alkyl groups
publisher University of North Texas
publishDate 1997
url https://digital.library.unt.edu/ark:/67531/metadc278441/
work_keys_str_mv AT thorntonterrylterrylee1962 mixedalkyllithimlithiumalkoxideaggregateswithlessstericallycrowdedalkylgroups
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