Understand the inversion mechanism of P-stereogenic compound using kinetic studies and in silico modeling

Understand the inversion mechanism of P-stereogenic compound using kinetic studies and in silico modeling

La thèse consiste en l'étude de la racémisation d'hydrogéno-phénylphosphinates d'alkyle, des molécules centrées sur un phosphore stéréogénique. Pour cela, nous avons synthétisé les composés d'intérêt puis étudié leur cinétique de racémisation en utilisant l'HPLC chirale et l...

Full description

Bibliographic Details
Main Author:	Javierre, Guilhem
Other Authors:	Ecole centrale de Marseille
Language:	en
Published:	2018
Subjects:	Phosphore Oxyde de phosphine DFT Cinétique Racémisation Phosphorus Phosphine oxide Kinetic Racemization
Online Access:	http://www.theses.fr/2018ECDM0001/document

Similar Items

P-Stereogenic diamondoid phosphines
by: Kateryna D. Butova, et al.
Published: (2020-09-01)

Mechanistic Studies for Palladium Catalyzed Copolymerization of Ethylene with Vinyl Ethers
by: Andleeb Mehmood, et al.
Published: (2020-10-01)

Dinuclear Silver(I) Nitrate Complexes with Bridging Bisphosphinomethanes: Argentophilicity and Luminescence
by: Kristina F. Baranova, et al.
Published: (2020-09-01)

Adsorption of Phosphine on a BN Nanosurface
by: Sahar Mohajeri, et al.
Published: (2018-02-01)

Carborane derivatives with electron rich moieties. Synthesis, properties and electronic communication
by: Popescu, Radu‐Adrian
Published: (2013)

The DFT study on racemisation of atropisomeric biaryls
by: Katarzyna Kapłon, et al.
Published: (2015-09-01)

Synthesis of γ-hydroxypropyl P-chirogenic (±)-phosphorus oxide derivatives by regioselective ring-opening of oxaphospholane 2-oxide precursors
by: Iris Binyamin, et al.
Published: (2015-07-01)

Kinetic studies on the substitution reactions of the CIS - dihalotetracarbonylmanganate (I) ions with phosphine and phosphite ligands.
by: Smith, Frank Edwin.
Published: (1968)

Utilisation de phosphore blanc et d'aminophosphines pour la formation de nanocristaux d'InP
by: Dreyfuss, Sébastien
Published: (2017)

Detection of Ammonia and Phosphine Gas using Heterojunction Biomolecular Chain with Multilayer GaAs Nanopore Electrode
by: Debarati Dey, et al.
Published: (2017-01-01)

Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo<sub>3</sub>PdS<sub>4</sub>}
by: Airat M. Kuchkaev, et al.
Published: (2021-01-01)

Preparation of phosphines through C–P bond formation
by: Iris Wauters, et al.
Published: (2014-05-01)

Organophosphorus Chemistry for the Synthesis of Dendrimers
by: Jean-Pierre Majoral, et al.
Published: (2012-11-01)

P-Stereogenic Phosphines for the Stabilisation of Metal Nanoparticles. A Surface State Study
by: Eva Raluy, et al.
Published: (2016-12-01)

Fluorine-Substituted Arylphosphine for an NHC-Ni(I) System, Air-Stable in a Solid State but Catalytically Active in Solution
by: Kouki Matsubara, et al.
Published: (2019-09-01)

Synthèse et étude de phosphines organométalliques électrocommutables pour la catalyse
by: Tohme, Ayham
Published: (2014)

Synthesis and Properties of P-Stereogenic Cyclic Phosphines
by: Kato, Ryosuke
Published: (2016)

La réaction phosphine imide en milieu CO2 supercritique
by: Scondo, Alexandre
Published: (2008)

Phosphinate-containing heterocycles: A mini-review
by: Olivier Berger, et al.
Published: (2014-03-01)

Synthesis, characterisation and application of functionalised phosphine ligands
by: Miller, Stuart Frank
Published: (2011)

Studies in the synthesis of the phosphinamides and related compounds /
by: Sarkis, Adib Jabbur
Published: (1956)

Phosphorus-based Flame Retardancy Mechanisms—Old Hat or a Starting Point for Future Development?
by: Bernhard Schartel
Published: (2010-09-01)

Photophysical Properties and Kinetic Studies of 2-Vinylpyridine-Based Cycloplatinated(II) Complexes Containing Various Phosphine Ligands
by: Vahideh Dolatyari, et al.
Published: (2021-04-01)

Stoichiometric and Catalytic Synthesis of Alkynylphosphines
by: Annie-Claude Gaumont, et al.
Published: (2012-12-01)

Catalyst-free photooxidation of triarylphosphines under aerobic conditions
by: Aishun Ding, et al.
Published: (2015-11-01)

H/D Isotope Effects on <sup>1</sup>H-NMR Chemical Shifts in Cyclic Heterodimers and Heterotrimers of Phosphinic and Phosphoric Acids
by: Valeriia V. Mulloyarova, et al.
Published: (2020-04-01)

DoM chemistry in the preparation of phosphine ligands for Pd-catalysed reactions
by: Hughes, Tanya
Published: (2010)

Sterically hindered and unsymmetrical phosphines: synthetic and catalytic aspects
by: Evans, Stephen John
Published: (2008)

The infrared spectrum of deutero-phosphine /
by: Ward, William Morgan
Published: (1951)

Effects of coriolis resonance in the low frequency vibration-rotation bands of phosphine /
by: Hoffman, James Morton
Published: (1960)

The donor ability of tertiary phosphine and arsine chalcogenides /
by: Nicpon, Philip Edward
Published: (1966)

Transition metal complexes containing cationic phosphine, potentially tridentate phosphine, or phosphine oxide ligands /
by: Berglund, Donna Lou
Published: (1969)

Development and characterization of a novel flame retardant EVM-based formulation : investigation and comprehension of the flame retardant mechanisms
by: Cérin-Delaval, Oriane
Published: (2010)

Activation of carbon-fluorine bonds using ruthenium dihydride complexes
by: Kirkham, Matthew Samuel
Published: (2001)

Développement de phosphasucres inédits pour la synthèse d’analogues de nucléosides à visée antivirale
by: Dayde, Bénédicte
Published: (2010)

Michaelis-Arbuzov-Type Reaction of 1-Imidoalkyltriarylphosphonium Salts with Selected Phosphorus Nucleophiles
by: Jakub Adamek, et al.
Published: (2019-09-01)

Predicting Absorption-Distribution Properties of Neuroprotective Phosphine-Borane Compounds Using In Silico Modeling and Machine Learning
by: Raheem Remtulla, et al.
Published: (2021-04-01)

A novel family of (1-aminoalkyl)(trifluoromethyl)- and -(difluoromethyl)phosphinic acids – analogues of α-amino acids
by: Natalia V. Pavlenko, et al.
Published: (2014-03-01)

P-Fluorous Phosphines as Electron-Poor/Fluorous Hybrid Functional Ligands for Precious Metal Catalysts: Synthesis of Rh(I), Ir(I), Pt(II), and Au(I) Complexes Bearing P-Fluorous Phosphine Ligands
by: Shin-ichi Kawaguchi, et al.
Published: (2017-01-01)

The tert-butylaminomethyl(mesityl)phosphinic acid ester and formation of its zinc dichloride complex: syntheses and characterization
by: Lutter Michael, et al.
Published: (2018-08-01)